Tris(dibenzylideneacetone)dipalladium(0),C51H42O3Pd2,51364-51-3

51364-51-3

Properties
Synonyms: Bis[tris(dibenzylideneacetone)palladium(0)] Pd2(dba)3
CAS Number: 51364-51-3
Formula: C51H42O3Pd2
Formula Weight: 915.74
Form: Powder
Melting point: 152-155°
Sensitivity: Air & Moisture Sensitive
Solubility: Soluble in chlorinated solvents, benzene and THF
Purity: 23.24%

Applications
Tris(dibenzylideneacetone)dipalladium(0) is the most widely used Pd0 precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. It is used as a catalyst precursor for palladium-catalyzed carbon-nitrogen bond formation, conversion of aryl chlorides, triflates and nonaflates to nitroaromatics. It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins. It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.

Notes
Handle under nitrogen atmosphere and protect from moisture and air.

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